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EQUILIBRIUM AND SPONTANEOUS CHANGE According to the first law of thermodynamics, the incremental change dU in the internal energy of a closed system during any physical or chemical process is given by dU = d−q +d−w, (A1) The definitive reference for more than half a century,—updated for the first time in more than a decade. Complete solutions to all the new problems to the 6th edition are Jan 1, 1999 · In engineering practice and thermodynamics texts, it is assumed that, for the expansion of a gas from a high-pressure tank to a low-pressure tank (through a valve) under adiabatic conditions, the Solutions to Introduction to Chemical Engineering Thermodynamics (9780073104454), Pg. • Objectives: 1. 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